ALKENE ALKYNE OXIDATION

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Lect # 1
Content Covered:

Alkenes , Preparation of Alkene , Pyrolysis of ester , Pyrolysis of xanthates (Chaugave reaction ) , Cope reaction , Didehalogenations

Duration: 37 Minutes

Lect # 2
Content Covered:

Chemical reactions of Alkenes , Electrophilic addition reaction (AE Rxn), Classical carbocation mechanism , Non-Classical carbocation mechanism , Markowni Koff's rule , Addition of H–X, Antimarkowni Koff's rule

Duration: 52 Minutes

Lect # 3
Content Covered:

Addition of H2O on Alkenes , Acid-catalysed hydration of Alkenes , Oxymercuration- Demercuration reaction (OM/DM), Hydroboration -oxidation (HBO), Alkoxymercuration Demercuration , Addition of X2 on Alkenes

Duration: 47 Minutes

Lect # 4
Content Covered:

Addition of HOX on alkenes , Stereoselectivity , Order of rate of addition of X2 on alkene , Chemical reaction of Alkynes , Addition of H-X on alkynes , Addition of H2O on alkynes , Hydration of alkyne with dil H2SO4 and HgSO4, Hydroboration – Oxidation

Duration: 48 Minutes

Lect # 5
Content Covered:

Addition of HOX on alkynes , Preparation of alkynes , Isomerisation

Duration: 24 Minutes

Lect # 6
Content Covered:

Isomerisation mechanism , Reaction of terminal alkynes , Dienes , Conjugated diene , Addition NOCl on alkene , Allylic substitution , NBS- N-bromosuccinimide

Duration: 35 Minutes

Lect # 7
Content Covered:

Reaction of NBS, MnO2- Oxidising agent , Carbenes , Sources of carbenes , Types of carbenes

Duration: 21 Minutes

Lect # 8
Content Covered:

Reaction of carbene , Reimmer-Tiemann reaction , Carbyl amine reaction , OXIDATION , definition of oxidation , Oxidation of alkenes and alkynes , Ozonolysis of Alkenes and alkynes , Oxidation of Ketone , Perhydroxylation of Alkenes (Formation of diols), Baiyer reaction – Baeyer's reagent , Osmium tetraoxide (OsO4), Epoxidation by per acid

Duration: 49 Minutes

Lect # 9
Content Covered:

Oxidation-strong oxidising agent , Potassium dichromate K2Cr2O7/H2SO4, Alkaline KMnO4/ OH-, H2CrO4 or CrO3 + H2O, Table of oxidising agents , Oxidation of alcohols , Mild oxidising agents , Oxidation of periodic acid HIO4, Oxidation of aldehydes , Oxidation with NBS, Tollen's reagent , Fehling's Reagent , Benedict's solution , Schiff's reagent

Duration: 38 Minutes

Lect # 10
Content Covered:

Oxidation of seleniumdioxide SeO2, Side-Chain oxidation

Duration: 13 Minutes

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