AROMATIC COMPOUND

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Lect # 1
Content Covered:

Aromaticity , Benzenoids and Non-Benzenoids , NMR-definition of Aromaticity , Anti Aromaticity , Polycyclic aromatic compound , Azulenes , Reaction of AgNO3 and Na-metal , (n)-Annulenes , Peripheral aromaticity

Duration: 44 Minutes

Lect # 2
Content Covered:

Electrophilic aromatic substitution reaction , Halogenation of Benzene , Baltz-Schiemann reaction , Nitration of benzene , Kinetic Isotope effect , Sulphonation of benzene , Friedel-Craft reaction (F.C. Rxn), F.C. Alkylation

Duration: 49 Minutes

Lect # 3
Content Covered:

Ring-Closure at C-1 and C–2, Dehydrogenation , Limitations of F.C. reaction , Friedel Craft Acylation , Ring closure , Directive influence or Directive effect , Table of activating and deactivating groups

Duration: 44 Minutes3

Lect # 4
Content Covered:

Ortho-para ratio , Direction effect on disubstituted benzene , Directive influence in monosubstituted benzene , Directive influence in naphthalene , Directive influence in diphenyl , Directive influence in Anthracene and phenanthrene, Directive influence in pyridine & pyrrole , SN2 Ar reaction , PHENOL, Preparation of phenol

Duration: 37 Minutes

Lect # 5
Content Covered:

Preparation of phenol from acid hydrolysis of cumene , Chemical reaction of phenol , Halogenation of phenol , Protection of –OH group, Nitration of Phenol , Sulphonation of Phenol, Reimer-Tiemann Reaction , Reimer-Tiemann formylation , Reimer-Tiemann carboxylation , Comparison of Reimer-Tiemann and carbyl amine reactions , Kolbe-Schmidt reaction , Some medicinally important compounds , Aspirine, Salol, Oil of winter green

Duration: 39 Minutes

Lect # 6
Content Covered:

Nitrosation of phenol , Use of phenol as nucleophile, ANILINE, Preparation of aniline from reduction of nitrobenzene , Selective reduction , Chemical reactions of aniline , Halogenation of Aniline , Nitration of Aniline, Sulphonation of Aniline

Duration: 26 Minutes

Lect # 7
Content Covered:

Fries rearrangment reaction in Phenol , Claisen rearrangement , Diazotisation of Aniline , Reaction of Benzene diazonium chloride (BDC) , Sandmeyer reaction , Baltz-scheimann reaction , Experimental evidence of formation of phenyl cation , Amination – Deamination

Duration: 43 Minutes

Lect # 8
Content Covered:

AMINES, Preparation of Amines , Hofmann Bromamide reaction , Hofmann methylation , Gabriel phthalimide reaction , Coupling reaction of BDC

Duration: 32 Minutes

Lect # 9
Content Covered:

Test of Amines ,Isocyanide Test of 1º Amine , Test with nitrous acid HNO2, CYANIDES and ISOCYANIDES , Preparation of cyanides and isocyamide , Hydrolysis of cyanides and isocyanides , IPSO-Substitution

Duration: 23 Minutes

Lect # 10
Content Covered:

Basic Strength, Definition of bases , Scales of basic strength , Organic Nitrogenous bases

Duration: 12 Minutes

Lect # 11
Content Covered:

Basic strength of Aliphatic amines , Basic strength of Aromatic amines , SH of H2O, SIR effect on Aromatic amines , Basic strength of pyridine and pyarole

Duration: 43 Minutes

Lect # 12
Content Covered:

Amidine-basic strength , Guanidine- basic strength , Kb order , Proton sponges , Site of protonation , Feasibility of reaction

Duration: 31 Minutes

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