G R ALKANE REDUCTION

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All Lectures


Lect # 1
Content Covered:

Organometallic compounds , Preparation of G.R.

Duration: 12 Minutes

Lect # 2
Content Covered:

Preparation of GR, Solvents of GR, Reaction of GR, Acid-base reaction of GR, Zerewitinoff's active hydrogen determination

Duration: 33 Minutes

Lect # 3
Content Covered:

Nucleophilic addition reaction of GR, SN2- Th reaction of GR

Duration: 30 Minutes

Lect # 4
Content Covered:

Unstable GR, Mono GR is not possible with dihalide , Reaction of GR with CO2, Reaction of GR with O2, Reaction of GR with RCN, Digrignard reagent , Reactions of digrignard reagent

Duration: 40 Minutes

Lect # 5
Content Covered:

Attack of GR on weak bond, 1,2-addtion & 1,4-additon , Reaction of GR with metal halides , REDUCTION , Definition of reduction , Table of reducing agents , Catalytic hydrogenation

Duration: 42 Minutes

Lect # 6
Content Covered:

Catalylic hydrogenation , Stereoselectivity ,) Partial hydrogenation , Lindlar's catalyst , P-2 catalyst (Nickle Boride), Birch reduction

Duration: 44 Minutes

Lect # 7
Content Covered:

Hydroboration Reduction (HBR), Transfer Hydrogenation, Clemmensen reduction , Wolf-Kishner reduction, Lithium aluminium hydride (LiAlH4)

Duration: 54 Minutes

Lect # 8
Content Covered:

Sodiumboro hydride (NaBH4) (SBH), Triphenyltin hydride Ph3SnH (TPH), DiBAl-H- Diisobutyl Aluminium hydride , Red –P + HI, Mozingo reduction , MPV- reduction , Oppeneaus Oxidation , Bauvealt-Blanc reduction , ALKANES, Free Radicals , Formation of free radicals , F.R. Catalyst/ Initiators / Promotors , F.R. Inhibitors/ Scavangers/Poisons , Stability of free radicals , Reactions of free radicals , Combination Reactions , Disproportionation reaction

Duration: 59 Minutes

Lect # 9
Content Covered:

Reactions of Free radicals , Stability of free radicals , Preparation of Alkanes , Wurtz Reaction (WR), Wurtz-Fitting reaction , Fitting reaction , Frankland reaction , Kolbe's Electrolytic synthesis (KES), Corey-House Reaction

Duration: 41 Minutes

Lect # 10
Content Covered:

Corey House reaction, Decarboxylation , Decarboxylation by soda lime , Decarboxylation by heating

Duration: 40 Minutes

Lect # 11
Content Covered:

Properties of Alkanes , Chemical properties of Alkanes , Free Radical substitution reaction , PE-diagrams , Reactivity order , Conditions of halogenation

Duration: 25 Minutes

Lect # 12
Content Covered:

reactivity and selectivity , Percentage yield , Quantum yield , Isomerisation reaction of alkanes , Aromatisation reaction of alkanes , Petroleum , Physical Properties of alkanes

Duration: 39 Minutes

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